(N,N-Diethyl­dithio­carbamato-κ2 S,S′)iodido(1,10-phenanthroline-κ2 N,N′)copper(II)

نویسندگان

  • Le-Qing Fan
  • Ji-Huai Wu
  • Yun-Fang Huang
  • Seik Weng Ng
چکیده

The copper(II) atom in the title compound, [Cu(C(5)H(10)NS(2))I(C(12)H(8)N(2))], is chelated by the N-heterocycle and the dithio-carbamate anion in a slightly distorted tetragonal coordination. The tetragonal-pyramidal coorination is completed by the iodine atom in the apical position. One ethyl group is disordered over two positions with site occupancies of 0.31 (2) and 0.69 (2).

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Iodido(1,10-phenanthroline-κ2 N,N′)(piperine-1-carbodithioato-κ2 S,S′)copper(II)

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In the title complex, [Cu(C(12)H(13)NO(5))(C(12)H(8)N(2))]·0.5H(2)O, the Cu(II) ion is five-coordinated by one N atom and two O atoms from a tridentate Schiff base ligand, derived from the condensation of l-threonine and o-vanillin, and two N atoms from a 1,10-phenanthroline ligand in a distorted square-pyramidal geometry. In the crystal, inter-molecular O-H⋯O hydrogen bonds form a one-dimensio...

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عنوان ژورنال:

دوره 65  شماره 

صفحات  -

تاریخ انتشار 2009